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Details on Person In the presence of sulfhydryl compounds such as cysteine, do...
| Class:Id | Summation:5662897 |
|---|---|
| _displayName | In the presence of sulfhydryl compounds such as cysteine, do... |
| _timestamp | 2015-01-26 11:52:56 |
| created | [InstanceEdit:5662886] Jupe, Steve, 2015-01-14 |
| literatureReference | [LiteratureReference:5662879] A facile one-step synthesis of cysteinyldopas using mushroom tyrosinase [LiteratureReference:5665908] A pulse radiolysis investigation of the oxidation of the melanin precursors 3,4-dihydroxyphenylalanine (dopa) and the cysteinyldopas |
| modified | [InstanceEdit:5665927] Jupe, Steve, 2015-01-20 [InstanceEdit:5668549] Jupe, Steve, 2015-01-26 |
| text | In the presence of sulfhydryl compounds such as cysteine, dopaquinone reacts to produce several cysteinyldopa (CD) isomers, 5-S-cysteinyldopa (5SCD) and 2-S-cysteinyldopa (2SCD) in 74% and 14% yields, respectively (Ito & Prota 1977, Thompson et al. 1985). 2,5-S,S'-dicysteinyldopa (DiCD) is produced in a 5% yield. Further oxidation of the thiol adducts leads to the formation of pheomelanin via benzothiazine intermediates. |
| (summation) | [Reaction:5662908] Dopaquinone, cysteine form CD isomers [Homo sapiens] |
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